Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia     

Geordie Mark  Nicholas H. S. Oliver  Patrick J. Williams 《Mineralium Deposita》2006,40(8):769-801

The Ernest Henry Cu–Au deposit was formed within a zoned, post-peak metamorphic hydrothermal system that overprinted metamorphosed dacite, andesite and diorite (ca 1740–1660 Ma). The Ernest Henry hydrothermal system was formed by two cycles of sodic and potassic alteration where biotite–magnetite alteration produced in the first cycle formed ca 1514±24 Ma, whereas paragenetically later Na–Ca veining formed ca 1529 +11/−8 Ma. These new U–Pb_titanite age dates support textural evidence for incursion of hydrothermal fluids after the metamorphic peak, and overlap with earlier estimates for the timing of Cu–Au mineralization (ca 1540–1500 Ma). A distal to proximal potassic alteration zone correlates with a large (up to 1.5 km) K–Fe–Mn–Ba enriched alteration zone that overprints earlier sodic alteration. Mass balance analysis indicates that K–Fe–Mn–Ba alteration—largely produced during pre-ore biotite- and magnetite-rich alteration—is associated with K–Rb–Cl–Ba–Fe–Mn and As enrichment and Na, Ca and Sr depletion. The aforementioned chemical exchange almost precisely counterbalances the mass changes associated with regional Na–Ca alteration. This initial transition from sodic to potassic alteration may have been formed during the evolution of a single fluid that evolved via alkali exchange during progressive fluid-rock interaction. Cu–Au ore, dominated by co-precipitated magnetite, minor specular hematite, and chalcopyrite as breccia matrix, forms a pipe-like body at the core of a proximal alteration zone dominated by K-feldspar alteration. Both the core and K-feldspar alteration overprint Na–Ca alteration and biotite–magnetite (K–Fe) alteration. Ore was associated with the concentration of a diverse range of elements (e.g. Cu, Au, Fe, Mo, U, Sb, W, Sn, Bi, Ag, F, REE, K, S, As, Co, Ba and Ca). Mineralization also involved the deposition of significant barite, K(–Ba)–feldspar, calcite, fluorite and complexly zoned pyrite. The complexly zoned pyrite and variable K–(Ba)–feldspar versus barite associations are interpreted to indicate fluctuating sulphur and/or barium supply. Together with the alteration zonation geochemistry and overprinting criteria, these data are interpreted to indicate that Cu–Au mineralization occurred as a result of fluid mixing during dilation and brecciation, in the location of the most intense initial potassic alteration. A link between early alteration (Na–Ca and K–Fe) and the later K-feldspathization and the Cu–Au ore is possible. However, the ore-related enrichments in particular elements (especially Ba, Mn, As, Mo, Ag, U, Sb and Bi) are so extreme compared with earlier alteration that another fluid, possibly magmatic in origin, contributed the diverse element suite geochemically independently of the earlier stages. Structural focussing of successive stages produced the distinctive alteration zoning, providing a basis both for exploration for similar deposits, and for an understanding of ore genesis.  相似文献   

Laboratory Studies Of Wind Stress Over Surface Waves   总被引：4，自引：0，他引：4  

B. Mete Uz  Mark A. Donelan  Tetsu Hara  Erik J. Bock 《Boundary-Layer Meteorology》2002,102(2):301-331

Simultaneous laboratory observations of wind speed, wind stress, and surfacewind-wave spectra are made under a variety of wind forcing patterns using cleanwater as well as water containing an artificial surfactant. Under typical experimentalconditions, more than half of the total stress is supported by the wave-induced stressrather than by the surface viscous stress. When the surfactant reduces the shortwind-wave spectra, the wind stress also decreases by as much as 20–30% at agiven wind speed. When the wind forcing is modulated in time, the wind stresstends to be higher under decreasing wind than under increasing wind at a givenwind speed, mainly because the response of short wind-wave spectra to varyingwind forcing is delayed in time. These examples clearly demonstrate that therelationship between the wind speed and the wind stress can be significantlymodified if the surface wave field is not in equilibrium with the wind forcing.Next, we examine whether the wind stress is estimated accurately if the wave-inducedstress by all surface wave components is explicitly evaluated by linear superpositionand is added to the surface viscous stress. It is assumed that the surface viscous stressis uniquely related to the wind speed, and that the wind input rate is determined by thelocal, reduced turbulent stress rather than the total stress. Our wind stress estimatesincluding the wave contributions agree well with observed wind stress values, evenif the surface wave field is away from its equilibrium with the wind in the presenceof surface films and/or under time-transient wind forcing. These observations stronglysuggest that the wind stress is accurately evaluated as a sum of the wave-induced stressand the surface viscous stress. At very high winds, our stress estimates tend to be lowerthan the observations. We suspect that this is because of the enhancement of wind stressover very steep (or breaking) short wind-waves.  相似文献   

Rates of Deglaciation during the Last Glaciation and Holocene in the Cordillera Vilcanota-Quelccaya Ice Cap Region, Southeastern Perú     

Bryan G. Mark  Geoffrey O. Seltzer  Donald T. Rodbell  Adam Y. Goodman 《Quaternary Research》2002,57(3):287

Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10⁻⁵ to 114×10⁻⁵ km³ yr⁻¹ and 112×10⁻⁵ to 247×10⁻⁵ km³ yr⁻¹ for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10⁻⁵ to 220×10⁻⁵ km³ yr⁻¹, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.  相似文献   

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol     

Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.  相似文献   

ENSO impacts on salinity in Tampa Bay, Florida     

Nancy Schmidt  Mark E. Luther 《Estuaries and Coasts》2002,25(5):976-984

Estuarine salinity distributions reflect a dynamic balance between the processes that control estuarine circulation. At seasonal and longer time scales, freshwater inputs into estuaries represent the primary control on salinity distribution and estuarine circulation. El Niño-Southern Oscillation (ENSO) conditions influence seasonal rainfall and stream discharge patterns in the Tampa Bay, Florida region. The resulting variability in freshwater input to Tampa Bay influences its seasonal salinity distribution. During El Niño events, ENSO sea surface temperature anomalies (SSTAs) are significantly and inversely correlated with salinity in the bay during winter and spring. These patterns reflect the elevated rainfall over the drainage basin and the resulting elevated stream discharge and runoff, which depress salinity levels. Spatially, the correlations are strongest at the head of the bay, especially in bay sections with long residence times. During La Niña conditions, significant inverse correlations between ENSO SSTAs and salinity occur during spring. Dry conditions and depressed stream discharge characterize La Niña winters and springs, and the higher salinity levels during La Niña springs reflect the lower freshwater input levels.  相似文献   

Problems with argon: K-Ar ages in Gulf Coast shales     

Mark Wilkinson 《Chemical Geology》2002,191(4):277-283

K-Ar ages of Gulf Coast shales do not correspond to diagenetic ‘events’, but are a combination of inherited detrital ages and authigenic overprints. The key to understanding K-Ar ages of shales is the fate of the ⁴⁰Ar when the host minerals dissolve or react during the illitisation reaction: is ⁴⁰Ar incorporated within the illite, or is it lost to the porewaters? Ages are modelled as due to a single illitisation reaction, assuming a uniform precursor sediment and open-system import of K. Both whole-rock and clay mineral fraction data can be reproduced by modelling. The ⁴⁰Ar incorporated into illite is a surprisingly high proportion (75-100%) of that produced within detrital phases (smectite, K-feldspar, mica), perhaps implying that the illitisation reaction is a solid-state transformation, or that ⁴⁰Ar is imported into the shales along with incoming K. The model does not provide a good fit to the data below 4000 m, when the illitisation reaction is apparently complete, but shales lose ⁴⁰Ar by solid-state diffusion or recrystallisation.  相似文献   

Climate change impacts on U.S. Coastal and Marine Ecosystems   总被引：1，自引：0，他引：1  

Donald Scavia  John C. Field  Donald F. Boesch  Robert W. Buddemeier  Virginia Burkett  Daniel R. Cayan  Michael Fogarty  Mark A. Harwell  Robert W. Howarth  Curt Mason  Denise J. Reed  Thomas C. Royer  Asbury H. Sallenger  James G. Titus 《Estuaries and Coasts》2002,25(2):149-164

Increases in concentrations of greenhouse gases projected for the 21st century are expected to lead to increased mean global air and ocean temperatures. The National Assessment of Potential Consequences of Climate Variability and Change (NAST 2001) was based on a series of regional and sector assessments. This paper is a summary of the coastal and marine resources sector review of potential impacts on shorelines, estuaries, coastal wetlands, coral reefs, and ocean margin ecosystems. The assessment considered the impacts of several key drivers of climate change: sea level change; alterations in precipitation patterns and subsequent delivery of freshwater, nutrients, and sediment; increased ocean temperature; alterations in circulation patterns; changes in frequency and intensity of coastal storms; and increased levels of atmospheric CO₂. Increasing rates of sea-level rise and intensity and frequency of coastal storms and hurricanes over the next decades will increase threats to shorelines, wetlands, and coastal development. Estuarine productivity will change in response to alteration in the timing and amount of freshwater, nutrients, and sediment delivery. Higher water temperatures and changes in freshwater delivery will alter estuarine stratification, residence time, and eutrophication. Increased ocean temperatures are expected to increase coral bleaching and higher CO₂ levels may reduce coral calcification, making it more difficult for corals to recover from other disturbances, and inhibiting poleward shifts. Ocean warming is expected to cause poleward shifts in the ranges of many other organisms, including commercial species, and these shifts may have secondary effects on their predators and prey. Although these potential impacts of climate change and variability will vary from system to system, it is important to recognize that they will be superimposed upon, and in many cases intensify, other ecosystem stresses (pollution, harvesting, habitat destruction, invasive species, land and resource use, extreme natural events), which may lead to more significant consequences.  相似文献   

Epibenthic fishes and decapod crustaceans in northern estuaries: A comparison of vegetated and unvegetated habitats in maine     

Mark A. Lazzari 《Estuaries and Coasts》2002,25(6):1210-1218

Species richness and abundance of epibenthic fishes and decapod crustaceans were quantified with day-time beam trawl tows and throw traps to provide information on nekton assemblages inZostera marina and unvegetated sandy habitats in northern latitudes. Sampling at randomly selected stations with a 1.0-m beam trawl occurred in eelgrass (Zostera marina) and unvegetated sandy substrates of two mid-coastal Maine estuaries: Casco Bay and Weskeag River. Random 1.0-m throw trap samples were collected inZostera and adjacent unvegetated sandy substrates in Casco Bay and Weskeag River as well. Species richness and faunal abundances were positively associated with the occurrence ofZostera within Weskeag River and Casco Bay estuaries using both gear types. A total of 17 species of fishes and 6 species of decapods were collected in the two estuaries using both gears. Populations of most species were dominated by young-of-the-year and juvenile life history stages. Number and densities of fishes were higher inZostera, due primarily to the abundances of eelgrass residents such as threespine,Gasterosteus aculeatus, and fourspine sticklebacks,Apeltes quadracus, grubby,Myoxocephalus aenaeus, and cunner,Tautogolabrus adspersus. Crangon septemspinosa dominated decapod catch per unit effort and density in both estuaries and habitats.  相似文献   

Bringing NEOs into focus     

Duncan Steel  Mark Bailey 《Astronomy& Geophysics》2002,43(1):1.14-1.15

Duncan Steel and Mark Bailey report on the well-attended December 2001 G Discussion Meeting whose subject was near-Earth objects.  相似文献   

Comet Ikeya-Zhang rises for the NAM     

David Asher  Mark Bailey  Apostolos Christou  John McFarland  Mark Muir  Paul Rafferty 《Astronomy& Geophysics》2002,43(2):2.19-2.21

A possible naked-eye comet that may have been important in early cometary theory is announced by D J Asher , M E Bailey , A Christou , J McFarland , M F Muir and P P Rafferty .
Early indications sugest that Comet C/2002 (Ikeya-Zhang), discovered on 1 February 2002, may brighten to naked-eye visibility in late March 2002. It has also been suggested that it may be identical to one of the brighter comets of the 16th or 17th centuries, namely C/1532 R1 or C/1661 C1. The first of these, observed for more than 100 days towards the end of 1532, played an important role in the development of cometary theory. The second, although identified by Halley as having an orbit similar to that of the comet C/1532 R1, was not seen on its predicted return in 1788/1789 and so was presumably unrelated. Here we present long-term orbital integrations of C/2002 C1 which suggest that it orginated from the Oort cloud, and will be ejected again, within ˜0.3 Myr. There is a chance of 10–20% that it will end its life by falling into the Sun during a Halley-type phase of cometary evolution. The discovery of Ikeya-Zhang so closeto perigee by two amateur astonomers highlights the need for surveys covering both hemispheres to discover long-period and intermediate-period comets on Earth-crossing orbits.  相似文献